Material Safety Data Sheet
K-GRIP 203
Maple Leaf Sales II, inc.
Middleville, Michigan
Emergency Number: 1-800-424-9300
(Chemtrec)
MLS Number: MLS 660401B
MSDS Revision Date:
Section 1 – Product Identification
K-GRIP 203 Premium
Foam, Fabric & Trim Spray Adhesive (Non-Flammable)
Section 2 – Composition, Information on Ingredients
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1.
Methylene Chloride CAS#
75-09-2 % by
Weight: 70 Vapor
Pressure: 350 MMHG @ 20° C. Exposure
Limit: TLV-TWA:
50 ppm, 174 mg/cu.m OSHA PEL:
25 ppm, 87 mg/cu.m OSHA-STEL:
125 ppm, 437 mg/cu.m Skin: 15 min. LFL: 16.0
UFL: 66.0 SARA 313:
Yes |
2. 1,
2 Propylene Oxide CAS#
75-56-9 % by
Weight: < 1 Exposure
Limit: TLV-TWA:
20 ppm, 50 mg/cu.m OSHA PEL:
20 ppm, 50 mg/cu.m LFL: 3.0
UFL: 37.0 SARA 313: Yes |
HMIS Information:
Health: 3*, Flammability: 0, Reactivity: 0
Hazard
Rating: 0 – Minimal 1 – Slight 2 – Moderate 3 – High 4 – Extreme * – Chronic
These ratings should be used as part of a fully implemented
HMIS program.
LFL: Lower Flammability Limit Percent
UFL: Upper Flammability Limit Percent
Skin: Skin absorption must be considered as a route of
exposure.
C – Ceiling=Allow.
Exposure level should not be exceeded for any time period.
MFR: Manufacturer recommended exposure limit
STEL: Short Term Exposure Limit
SARA 313: Chemical is subject to reporting requirements of
section 313 of Title III of SARA 40 CFR Part 372.
Section 3 – Hazards Identification
Effects of Short Term Overexposure:
Ingestion:
Can cause gastrointestinal irritation, nausea, and
vomiting. Aspiration of material into
the lungs may cause chemical pneumonitis, which can be fatal.
Inhalation:
May be FATAL if too much is breathed! Preexisting heart conditions may be
aggravated by exposure to methylene chloride.
Exposure to chlorinated solvents may result in liver, kidney, and heart
sensitization. Overexposure may cause
unconsciousness and possible death. May
cause nose or throat irritation. High
concentrations may cause acute central nervous system depression with symptoms
of dizziness, headache, nausea, confusion.
Reduces the blood’s oxygen-carrying capacity by the formation of
carboxyhemoglobin. Reduced blood oxygen
levels may be harmful to users, especially those with existing heart disease.
Eye:
May cause eye irritation.
Skin:
May be absorbed through the skin in harmful amounts. May cause severe skin irritation.
Effects of Repeated Overexposure:
None currently known
Significant Laboratory Data with Possible Relevance to Human
Health:
Methylene chloride has been identified as a potential
carcinogen by the International Agency for Research on Cancer (IARC Group 2B –
Probable Human Carcinogen) and as a substance “Reasonably Anticipated to be a
Carcinogen” by the National Toxicology Program (NTP Group 2). These classifications are based on animal
studies (mice and rats) which indicated dose related incidences in lung, liver
and mammary tumors. Human
epidemiological studies indicate that the potential carcinogenic effect of methylene
chloride is dose dependent. This is
supported by the observation of an increased incidence of liver cancer
subsequent to high exposure (140 – 470 ppm) in a film production plant. Workers in another facility who were exposed
to a much lower concentration (26 ppm) showed no increase in cause specific
death.
The International Agency for Research on Cancer has
classified propylene oxide as a probable carcinogen (Group 2B) based upon
sufficient evidence from laboratory animal test data.
Section 4 – First Aid Measures
Ingestion:
If swallowed call
Inhalation:
Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep warm and quiet. Get medical attention immediately.
Eye:
Flush with large amounts of water, lifting upper and lower
lids occasionally. Continue for at
least 15 minutes. Get medical
attention.
Skin Contact:
Remove contaminated clothing.
Note to Physician:
Do not give stimulants.
Epinephrine or ephedrine may adversely affect the heart with fatal
results.
Section 5 – Fire Fighting Measures
NFPA Flammability Classification:
Not applicable
Flashpoint:
Not applicable
Extinguishing Media:
None should be needed.
Unusual Fire and Explosion Hazards:
This product contains halogenated hydrocarbons; contact with
aluminum may cause violent reaction and/or explosion.
Manufacturers of methylene chloride report no flash point
using the TOC, TCC, and COC methods.
However, it is known that methylene chloride does have a flammable
range: 14% (LFL) and 22% (UFL) at 25° C.
These represent very high concentrations that would present very serious
employee exposures relative to OSHA and ACGIH standards. Due to the lack of a typical flashpoint,
some confusion exists regarding the assignment of HMIS flammability ratings. Some suppliers have suggested that a
flammability rating of 1 should be assigned to methylene chloride. Others suggest that the lack of a true
flashpoint requires that a zero flammability rating be assigned. Prevent circumstances which would result in
methylene chloride concentrations within the flammable range as well as
exposure of liquid or vapor to sources of ignition. Please keep in mind that the presence of other flammable
substances in this or other product mixtures may alter the flashpoint and
increase the flash fire risk and the HMIS flammability rating.
Special Fire Fighting Procedures:
None known.
Section 6 – Accidental Release Measures
Steps to be Taken if Material is Released or Spilled:
The use of a NIOSH/MSHA approved, tc19c, air–supplied
breathing apparatus may be required.
Consult with a qualified occupational health and/or safety professional.
Wear respirators, eye, hand, and body protection appropriate
for the size of the spill and the exposures encountered.
Waste Disposal:
Dispose in accordance with federal, state and local
regulations.
Environmental Hazards:
None known
Section 7 – Handling and Storage
Precautions to be Taken in Handling and Storage:
None likely to be needed.
Other Precautions:
This product is intended to be used only by the professional
(industrial) applicator under properly controlled condition. A qualified occupational health professional
should evaluate exposures to this product.
The use of this product in confined areas may result in
dangerous airborne concentrations. This
may cause the serious health effects described in Section 3 of this MSDS.
Section 8 – Exposure Controls, Personal
Protection
Respiratory Protection:
If the TLV or PEL for the product or any component is
exceeded in the workplace air (see Section 2), a NIOSH/OSHA approved respirator
is advised. Engineering controls should
be implemented to reduce exposure. See
29 CFR 1910.1052 for specific OSHA requirements for employee exposure to
methylene chloride.
Ventilation:
Provide general dilution and local exhaust ventilation in
sufficient volume and pattern to keep concentrations of hazardous ingredients
listed in Section 2 below the lowest exposure limit stated. Remove decomposition products that are
generated when welding, cutting, or brazing objects coated with this
product. Refer to “Industrial
Ventilation – A Manual of Recommended Practice” ACGIH.
Hand Protection:
Wear appropriate impermeable gloves (North - Silver Shield).
Eye Protection:
Wear safety glasses meeting the specifications of ANSI z87.1
where no contact with the eye is anticipated.
Chemical safety goggles meeting the specifications of ANSI z87.1 should
be worn whenever there is a possibility of splashing or other contact with the
eyes.
Other Protective Equipment:
Eyewash facility, safety shower.
Section 9 – Physical and Chemical
Properties
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Color: Clear (amber) or red Vapor Density: Heavier than air. Boiling Range: Lower:
93° F Higher:
104° F Specific Gravity: 1.2 |
Evaporation Rate: Slower than diethyl ether. Volatile (% Volume): 66 VOC: .11 lb. /gal. (Less water & NPRS*) VOC: 13 g/l (Less water) calculated Weight (lb./gal.): 10.2 VOC: .11 lb. /gal. solids, 13 g/l solids calculated *Negligibly Photochemically Reactive Materials |
Section 10 – Stability and Reactivity
Stability:
Avoid open flames, welding arcs or other high temperature
sources which induce thermal decomposition.
Conditions to Avoid:
None known
Incompatibilities (Materials to Avoid):
Aluminum
This product contains halogenated hydrocarbons which may
react with aluminum. Avoid contact with
aluminum in situations in which pressures may be elevated or in which reactions
may be enclosed. Do not use spray
equipment systems containing aluminum parts.
Hazardous Decomposition Products:
Burning, including when heated by welding or cutting, will
produce smoke, carbon monoxide and carbon dioxide. In addition, phosgene, formaldehyde, hydrogen chloride, and
chlorine may be generated.
Hazardous Polymerization:
Will not occur
Conditions to Avoid:
This product contains halogenated hydrocarbons which may
decompose to form hydrogen chloride, chlorine, and phosgene when in contact
with hot surfaces, open flames, and U.V. radiation. Do not use this material near welding operations.
Section 11 – Toxicological Information
No information available.
Section 12 – Ecological Information
No information available.
Section 13 – Disposal Considerations
See Section 6.
Section 14 – Transport Information
DOT Hazard Class: 6.1
DOT Packing Group: 3
Section 15 – Regulatory Information
All ingredients in this product are listed on the US TSCA
Inventory.
All ingredients in this product are listed on the Canadian
Domestic Substance List.
Warning: This Product Contains:
Methylene chloride; 1, 2 propylene oxide; chemicals known to
the State of
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Methylene
Chloride CAS#
75-09-2 Detail
Inventory List Information: TSCA (8a
CAIR) TSCA (8a
PAIR) TSCA (8d) DSL |
1,2
Propylene Oxide CAS#
75-56-9 Detail
Inventory List Information: TSCA
(12b) TSCA (4) TSCA (4
term) TSCA (8a
CAIR) TSCA (8a
PAIR) TSCA (8d) DSL |
Detail
Inventory List Description:
TSCA –
Toxic Substances Control Act
12b –
Notices of Export
4 – Test
Rules
4 term –
TSCA 4 term
8a CAIR –
Comprehensive Assessment Information Rules
8d – Health
and Safety Reporting Rules
DSL –
Canadian Domestic Substance List
Section 16 – Other Information
Disclaimer of Warranty and Other Comments:
The information contained herein is, to the best of our
knowledge and belief, accurate. However,
because the conditions of handling and use are beyond our control, we make no
guarantee of results, and assume no liability for damages incurred by the use
of this material. It is the
responsibility of the user to comply with all federal, state, and local laws
and regulations.
The responsibility to provide a safe workplace remains with
the user. The user should consider the
health hazards and safety information contained herein as a guide and should
take those precautions required in an individual operation to instruct
employees and to develop work practice procedures for a safe work environment.
Abbreviations:
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ACGIH: American Conference of Governmental &
Industrial Hygienists. OSHA: Occupational Safety & Health Administration NIOSH: National Institute for Occupational Safety and
Health IARC: International Agency for Research on Cancer NTP: National Toxicology Program TLV: Threshold Limit Value (ACGIH) PEL: Permissible Exposure Limit (OSHA) |
TWA: Time Weighted Average STEL: Short Term Exposure Limit ppm:
parts per million mg/cum:
milligrams per cubic meter of air N/D: Not
Determined N/A: Not
Applicable HMIS: Hazardous Materials Identification System |