Material Safety Data Sheet

K-GRIP 710

Maple Leaf Sales II, inc.

Middleville, Michigan

Emergency Number: 1-800-424-9300 (Chemtrec)

MLS Number: MLS 661401B

MSDS Revision Date: 5/19/2000

Section 1 – Product Identification

K-GRIP 710 Multi-Purpose Citrus Cleaner Aerosol

Section 2 – Composition, Information on Ingredients

1. 4 – Isopropenyl, 1 - Methylcyclohexene CAS# 5989-27-5 % by Weight: 55 ACGIH TLV-TWA: No info ACGIH TLV-STEL: No info OSHA PEL-TWA: No info OSHA PEL-Ceiling: No info TLV-TWA: No info Skin: No 2. Propane CAS# 74-98-6 % by Weight: 15 ACGIH TLV-TWA: 2500 ppm ACGIH TLV-STEL: No info OSHA PEL-TWA: 1000 ppm OSHA PEL-Ceiling: No info TLV-TWA: No info Skin: No 3. Amine Alkylbenzene Sulfonate CAS# Not available % by Weight: 10 ACGIH TLV-TWA: No info ACGIH TLV-STEL: No info OSHA PEL-TWA: No info OSHA PEL-Ceiling: No info TLV-TWA: No info Skin: No

4. Nonionic Alkoxylate CAS# Not available % by Weight: 5 ACGIH TLV-TWA: No info ACGIH TLV-STEL: No info OSHA PEL-TWA: No info OSHA PEL-Ceiling: No info TLV-TWA: No info Skin: No 5. Glycol Ethers CAS# Not applicable % by Weight: 5 ACGIH TLV-TWA: No info ACGIH TLV-STEL: No info OSHA PEL-TWA: No info OSHA PEL-Ceiling: No info TLV-TWA: No info Skin: No

(See Section 16 for abbreviation legend)

HMIS Information:

Health: 2, Flammability: 4, Reactivity: 0

Hazard Rating: 0 – Minimal 1 – Slight 2 – Moderate 3 – High 4 – Extreme * – Chronic

This product contains one or more reported Carcinogens or suspected Carcinogens which are noted NTP, IARC, or OSHA in the Other Limits column above. This product contains one or more components that are classified as Hazardous Air Pollutants (HAP) and are noted as such in the Other Limits column above.

Section 3 – Hazards Identification

**EMERGENCY OVERVIEW**:

Keep from reach of children. Do not puncture, incinerate, or place aerosol product containers in compactors. Containers of this material may be hazardous when emptied since containers retain product residues (vapor, liquid, and/or solid). All hazard precautions given must be observed. Do not flame cut, braze, or use welding torch. Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal.

Effects of Overexposure:

Eye Contact:

Can cause severe irritation, redness, tearing, and blurred vision.

Skin Contact:

Prolonged or repeated contact can cause moderate irritation, defatting, dermatitis.

Inhalation:

Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, fatigue, nausea, headache, possible unconsciousness, and even asphyxiation. Amine alkylbenzene sulfonate contains <.3% isopropylamine CAS# 75-31-0. The OSHA PEL for isopropylamine is 5 ppm.

Ingestion:

No information

Effects of Overexposure – Chronic Hazards:

No information

Primary Routes of Entry:

Skin contact, inhalation, and eye contact

Section 4 – First Aid Measures

Eye Contact:

Flush with large amounts of water, lifting upper and lower lids occasionally. Get medical attention.

Skin Contact:

Thoroughly wash exposed area with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.

Inhalation:

Remove individual to fresh air. If breathing is difficult, administer oxygen. Give artificial respiration if breathing has stopped. Keep person warm and quiet. Get medical attention.

Ingestion:

Do not induce vomiting. Give two glasses of water if conscious. Never give anything by mouth to an unconscious person. Get immediate medical attention.

Section 5 – Fire Fighting Measures

Flash Point:

-156° F (Pensky-Martens C.C.)

Flammable / Explosive Limits:

Lower Explosive Limit: .7%

Upper Explosive Limit: 9.5%

Auto-ignition Temperature:

Not determined

Extinguishing Media:

Carbon dioxide, dry chemical, foam, water fog

Unusual Fire and Explosion Hazards:

Vapors are heavier than air and travel along the ground or may be moved by ventilation and ignited by ignition sources at locations distant from material handling point. For aerosol products, exposure to temperatures over 130° F may cause containers to burst, releasing highly flammable gas. As with all unsaturated fats and oils, some porous materials such as rags, paper, insulation, or organic clay when wetted with this product may undergo spontaneous combustion. Keep such wetted materials well ventilated to prevent possible heat buildup.

Special Firefighting Procedures:

Wear self-contained breathing apparatus with a full facepiece operated in pressure-demand or other positive pressure mode when fighting fires. Keep fire exposed containers cool with water fog.

Section 6 – Accidental Release Measures

Steps to be Taken in Case Material is Released or Spilled:

Eliminate sources of ignition & ventilate area. Persons not properly equipped should be excluded from area. Stop spill at source - prevent spreading. Avoid inhalation of vapors. Avoid skin contact with liquid. Soak up on absorbent material and place into proper container for disposal. Use non-sparking scoops for flammable materials. Clean walking surfaces thoroughly to reduce slipping hazard.

Section 7 – Handling and Storage

Handling:

No information.

Storage:

Do not store above 120° F. Do not store in direct sunlight. Keep away from heat sources, open flame, sparks.

Section 8 – Exposure Controls, Personal Protection

Engineering Controls:

Provide sufficient mechanical ventilation (general and/or local exhaust) to maintain exposure below TLV(s).

Respiratory Protection:

If work place exposure limits of product or any component is exceeded, use a NIOSH/MSHA approved respirator. Consult your safety equipment supplier for recommendations.

Protective Gloves:

Wear impervious gloves if method of use involves skin contact with product. Consult your safety supply vendor for glove recommendations.

Eye Protection:

Wear safety glasses at minimum, more extensive protection may be necessary depending on how the product is to be used.

Other Protective Equipment:

Wear impervious clothing if bodily exposure is anticipated. Consult your safety supply vendor for recommendations.

Hygienic Practices:

Wash hands before eating or smoking. Smoke in designated areas only. Remove and launder clothing if contaminated.

Section 9 – Physical and Chemical Properties

Boiling Range: -44 – 400° F Odor: Citrus Appearance: Clear pale yellow Water Solubility: Dilutable Freeze Point: N.D. Vapor Pressure: N.D. Physical State: Liquid

Coefficient of Water / Oil Distribution: N.D. Vapor Density: Is heavier than air Odor Threshold: N.D. Evaporation Rate: Is faster than Butyl Acetate Specific Gravity: 0.8009 pH @ 0.0%: N.D. Viscosity: N.D.

(See Section 16 for abbreviation legend)

Section 10 – Stability and Reactivity

Conditions to Avoid:

Heat, sparks, welding arcs, open flame, static electricity, or other sources of ignition.

Incompatibility:

Acids, alkali, caustics, strong alkalis, strong oxidizers

Hazardous Decomposition Products:

Carbon monoxide and carbon dioxide, ammonia, sulfur dioxide, hydrogen sulfides, nitrogen oxide, nitrogen peroxide

Hazardous Polymerization:

Will not occur under normal conditions.

Stability:

This product is stable under normal storage conditions.

Section 11 – Toxicological Properties

No product or component toxicological information is available.

Section 12 – Ecological Information

No information.

Section 13 – Disposal Considerations

Disposal Method:

Dispose of in accordance with all local, state and federal regulations.

Section 14 – Transportation Information

DOT Proper Shipping Name: Aerosols

DOT Hazard Class: 2.1

Hazard Subclass: None

DOT UN/NA Number: UN1950

Packing Group: None

Resp. Guide Page: 126

Additional Information: For domestic ground and air shipment this product may be shipped as a consumer commodity ORM-D. Outer cartons must have the ORM-D or ORM-D Air designation. (Our original cartons are preprinted with the ORM-D designation for ground shipment)

Section 15 – Regulatory Information

U.S. Federal Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200)

CERCLA – SARA Hazard Category: This product has been reviewed according to the EPA “Hazard Categories” promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:

Immediate Health Hazard, Fire Hazard, Pressurized Gas Hazard

SARA Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:

Glycol ethers (CAS# Not applicable) – Weight is less than 5.0%

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12 (B) if exported from the United States: No information is available.

International Regulations:

Canadian WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings.

Canadian WHMIS Class: No information available.

Section 16 – Other Information

VOC Content: 70.2% by Weight, 561 G/L total product, 652 G/L less water and exempt, 0.71 lbs. /Can

Disclaimer of Warranty and Other Comments:

The information contained herein is, to the best of our knowledge and belief, accurate. However, because the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all federal, state, and local laws and regulations.

The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and to develop work practice procedures for a safe work environment.

Abbreviations:

ACGIH: American Conference of Governmental & Industrial Hygienists. OSHA: Occupational Safety & Health Administration NIOSH: National Institute for Occupational Safety and Health IARC: International Agency for Research on Cancer NTP: National Toxicology Program TLV: Threshold Limit Value (ACGIH) PEL: Permissible Exposure Limit (OSHA)

TWA: Time Weighted Average STEL: Short Term Exposure Limit ppm: parts per million mg/cum: milligrams per cubic meter of air N/D: Not Determined N/A: Not Applicable HMIS: Hazardous Materials Identification System